Making graphene in your kitchen

The interior courtyard of Trinity College in Dublin, Ireland on May 20, 2011
Atomic resolution, scanning transmission electron microscope image of part of a nanosheet of shear exfoliated graphene. The bright blobs (indicated by the arrow) are carbon atoms. Credit: CRANN/SuperSTEM

Graphene has been touted as a wonder material—the world's thinnest substance, but super-strong. Now scientists say it is so easy to make you could produce some in your kitchen.

Thus far, has proven elusively hard to manufacture on an . Methods have required a choice between high quality graphene in small quantities, or large batches with defects.

A team from England and Ireland, however, reported on Sunday they had used a blender to make microscopic sheets of graphene.

They placed powdered graphite, the stuff from which pencil lead is made, into a container with an "exfoliating liquid", and then mixed at high speed.

The result is miniscule sheets of graphene, each about a nanometre (a billionth of a metre) thick and 100 nanometres long, suspended in a liquid.

The force generated by the rotating blades separated the graphite into graphene layers without damaging their two-dimensional structure.

"We developed a new way of making graphene sheets," Trinity College Dublin chemical physics professor Jonathan Coleman, who co-authored the study in the journal Nature Materials, told AFP.

"This method gives lots of graphene with no defects."

The team used industrial equipment called shear mixers, but successfully repeated the experiment with a kitchen blender.

From lab to kitchen, 'wonder' nanomaterial
Production of graphene by shear exfoliation of graphite in the solvent N-methyl-pyrrolidone using a Silverson high shear mixer. In this experiment, 100 litres of graphene suspension were produced. Credit: CRANN

The liquid so produced can be spread onto surfaces as films of graphene sheets, like paint, or mixed with plastics to produce reinforced, composite materials.

"In the lab, we produced grams. However, when scaled up, tonnes will be produced," said Coleman.

Graphene is the world's thinnest substance, transparent but stronger than steel—a conductive super-material made of carbon just one atom thick.

There is a surge of interest in it to replace semiconductors in next-generation computers, touch screens, batteries and solar cells.

From lab to kitchen, 'wonder' nanomaterial
Transmission electron microscope image of nanosheets of shear exfoliated graphene. The scalebar is 100 nm. Credit: CRANN

Graphene was aired as a theoretical substance in 1947. But for decades, physicists thought it would be impossible to isolate, as such thin crystalline sheets were bound to be unstable.

The problem was resolved in 2004 by a pair of scientists who used ordinary sticky tape to lift a layer from a piece of graphite.

That layer was itself pulled apart using more tape, and the process repeated until just the thinnest of layers remained—a .

Coleman said a company that sponsored the study has applied for a patent on the new method.

More information: Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids, Nature Materials (2014) dx.doi.org/10.1038/nmat3944

Journal information: Nature Materials

© 2014 AFP

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